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In physics, an absorption edge is a sharp discontinuity in the absorption spectrum of a substance. These discontinuities occur at wavelengths where the energy of an absorbed photon corresponds to an electronic transition or ionization potential. When the radiation energy is far away from an absorption edge, the absorption spectrum follows a smoothly decreasing function that is proportional to . However, when the energy matches the binding energy of an electron in an atom the absorption spectrum sharply increases. This is due to the new absorption mechanism.
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