Why is "Allyl" trending?
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- Date: 2026-03-10 18:30:22
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Wikipedia Overview
In organic chemistry, an allyl group is a substituent with the structural formula −CH2−HC=CH2. It consists of a methylene bridge attached to a vinyl group. The name is derived from the scientific name for garlic, Allium sativum. In 1844, Theodor Wertheim isolated an allyl derivative from garlic oil and named it "Schwefelallyl". The term allyl applies to many compounds related to H2C=CH−CH2, some of which are of practical or of everyday importance, for example, allyl chloride.
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Team reports α-allylation of simple ketones and allyl alcohols on mesoporous silica - EurekAlert!
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Global Allyl Amyl Glycolate Market Gains Momentum as Demand - openPR.com
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Hard-to-make diastereomers: How a cage-like allyl reagent changes the outcome - Phys.org
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Copper-Catalyzed Asymmetric Allyl Addition of Imines with Allenylsilanes - ACS Publications
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Poly(di-allyl phthalate) hybrid nanocomposites with magnetic conductive coupling for absorption dominated EMI shielding - Nature
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Chemo‐ and Regiodivergent Allyl‐Propargyl Cross‐Coupling Reactions for the Construction of 1,4‐Enallenes and 1,5‐Enynes - Qian - 2025 - Angewandte Chemie International Edition - Wiley Online Library
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Epoxidation of allyl alcohol to glycidol over TPAOH-treated titanium silicalite-1 extrudates - Frontiers
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S-allyl cysteine and alliin enhance catalase activity and prevent aggregation to counter oxidative stress in alzheimer’s disease - Nature
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Structurally Flexible (Thiazol-2-ylidene)Pd(Allyl)Cl Complexes for Suzuki–Miyaura Cross-Coupling of Aryl Halides and Amides - ACS Publications
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Global Natural Allyl Heptylate Market Expands Steadily as Demand for Clean-Label Flavors and Fragrances Rises - openPR.com
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“Grafting-to” Polymers of Xylan- g -allyl Glycidyl Ether Toughen PEG Hydrogel via Microphase Separation: Thermoresponsive and Photoreactive Molecular Assembly in DLP 3D Printing - Wiley Online Library
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A bismuth-based analogue of the π -allyl cation - Nature
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Levulinic acid production from sugarcane bagasse: the role of acidity in 1-allyl-3-methylimidazolium ionic liquids - Frontiers
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Global Natural Allyl Hexanoate Market Gains Traction as Demand - openPR.com
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Deconstructive [4 + 3] Annulation of Isatin-Derived α-Keto Amides with CF3–Allyl–Pd Species | Organic Letters - ACS Publications
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Synthesis and Multifunctional Properties of Allyl‐Substituted Benzoxazines: Anti‐Corrosion, Anti‐Microbial and Computational Insights - Arumugam - 2025 - Polymers for Advanced Technologies - Wiley Online Library
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symmetric chiral ligand dictating allyl-allyl coupling - Nature
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Differential effects of S-allyl cysteine and cannabidiol on enterocytic and plasma amyloid-β in db/db diabetic mice - Nature
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Non-chelation control in allylations of α -oxy ketones using group-14 allylatranes - Nature
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Platform feedstock chemicals from global warming gas: a new paradigm in carbon utilization - EurekAlert!
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Catalytic Asymmetric Intramolecular Domino Allylic O-Alkylation/Allylic Dearomatization of Allyl Aryl Ethers - ACS Publications
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Enantio- and linear-selective allylic radical addition to imines using reductive cobalt catalysis - Nature
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Korean Scientists Transform CO₂ Into Liquid Gold - SciTechDaily
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Light-driven radical copper-catalyzed allylic amination via allylic copper intermediates - Nature
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A trimetallic bismuth(I)-based allyl cation - Nature
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Surface Coordination and Polymerization of Allyl Mercaptan Passivates the Oxidation of Copper - Wiley
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Measurement of diallyl disulfide and allyl methyl sulfide emanating from human skin surface and influence of ingestion of grilled garlic - Nature
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Allyl-Allyl Coupling Promoted by Catalyst Systems with two Palladium Atoms – A Plethora of Potentially Pericyclic Processes - Wiley Online Library
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Selective hydrosilylation of allyl chloride with trichlorosilane - Nature
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Photoredox-Catalyzed Allylic C–H Fluorosulfonylation of Alkenes: Accessing Allyl Sulfonyl Fluorides - ACS Publications
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Synthesis and Solvent Free DLP 3D Printing of Degradable Poly(Allyl Glycidyl Ether Succinate) - Wiley Online Library
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Enantioselective Synthesis of α -Hydroxy Allyl Ketones via BINAP-CuH-Catalyzed Hydroacylation - Wiley Online Library
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The catalytic enantioselective [1,2]-Wittig rearrangement cascade of allylic ethers - Nature
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Organosulfurs, S -allyl cysteine and N -acetyl cysteine sequester di-carbonyls and reduces carbonyl stress in HT22 cells - Nature
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Hypoglycemic and hypolipidemic effect of S-allyl-cysteine sulfoxide (alliin) in DIO mice - Nature
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1,5-Allyl Shift by a Sequential Achmatowicz/Oxonia-Cope/Retro-Achmatowicz Rearrangement - Wiley Online Library
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Anti-cancer activities of allyl isothiocyanate and its conjugated silicon quantum dots - Nature
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Allyl ether of mansonone G as a potential anticancer agent for colorectal cancer - Nature
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Nickel-Catalyzed Homo- and Cross-Coupling of Allyl Alcohols via Allyl Boronates - ACS Publications
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A General Strategy for the Asymmetric Preparation of α-Stereogenic Allyl Silanes, Germanes, and Boronate Esters via Dual Copper Hydride- and Palladium-Catalysis - Wiley Online Library
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Regiodivergent and Enantioselective Allylic C−H Alkylation of Allyl Ethers: Optimization, Scope, Mechanism and Application - Wiley Online Library
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Iridium-Catalyzed Chemo-, Diastereo-, and Enantioselective Allyl-Allyl Coupling: Accessing All Four Stereoisomers of ( E )-1-Boryl-Substituted 1,5-Dienes by Chirality Pairing - Wiley Online Library
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Turning glucosinolate into allelopathic fate: investigating allyl isothiocyanate variability and nitrile formation in eco-friendly Brassica juncea from South Korea | Scientific Reports - Nature
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Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms - Nature
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Appraisal of growth inhibitory, biochemical and genotoxic effects of Allyl Isothiocyanate on different developmental stages of Zeugodacus cucurbitae (Coquillett) (Diptera: Tephritidae) - Nature
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Photochemical Organocatalytic Regio- and Enantioselective Conjugate Addition of Allyl Groups to Enals - Wiley Online Library
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Catalytic deoxydehydration of glycerol to allyl alcohol in the presence of mono-oxygenated rhenium diphosphine complexes - ScienceDirect.com
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Reductive coupling of allenyl/allyl carbonate with alkyne under dual cobalt-photoredox catalysis - Nature
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Photochemical Organocatalytic Regio- and Enantioselective Conjugate Addition of Allyl Groups to Enals - Wiley Online Library
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A Precise Route to Tetrasubstituted Allyl Amines via Regioselective Dicarbofunctionalization of Masked Propargyl Amines - ACS Publications
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)-catalysed asymmetric Suzuki–Miyaura coupling with racemic allyl halides - Nature
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Field attraction of Eurydema ornata (Hemiptera: Pentatomidae) to allyl isothiocyanate - Nature
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Toughening of bismaleimide and benzoxazine alloy with allyl group by incorporation of polyrotaxane - ScienceDirect.com
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Allyl Chloride Market Size, Share | CAGR of 5.7% - Market.us
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Palladium-Catalyzed Regiodivergent Synthesis of 1,3-Dienyl and Allyl Esters from Propargyl Esters - Wiley Online Library
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A general leaving group assisted strategy for synthesis of pentafluorosulfanyl allylic compounds - Science | AAAS
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Lithium promoted mesoporous manganese oxide catalyzed oxidation of allyl ethers - Nature
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Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groups - Nature
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Cellulose extraction from wood chip in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl) - ScienceDirect.com
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Gold(III) π‐Allyl Complexes - Rodriguez - 2020 - Angewandte Chemie International Edition - Wiley Online Library
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Copper‐Catalyzed Enantioselective Allyl–Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N‐Heterocyclic Carbene Chiral Ligand - Yasuda - 2016 - Angewandte Chemie International Edition - Wiley Online Library
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An η3‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex - Wiley Online Library
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Catalytic diastereo- and enantioselective additions of versatile allyl groups to N–H ketimines - Nature
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Rhodium-Catalyzed β-Acylalkylation of Allylbenzene Derivatives with Allyl Alcohols via C–C Bond Cleavage - ACS Publications
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Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications - ACS Publications
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The role of allyl ammonium salts in palladium-catalyzed cascade reactions towards the synthesis of spiro-fused heterocycles - Nature
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Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides - Nature
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Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism - Nature
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Chemoselective Rearrangement Reactions of Sulfur Ylide Derived from Diazoquinones and Allyl/Propargyl Sulfides - ACS Publications
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Preparation and UV‐curing properties of rosin‐based allyl phthalate oligomer - Wiley Online Library
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A Thioether‐Catalyzed Cross‐Coupling Reaction of Allyl Halides and Arylboronic Acids - Wiley Online Library
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Synthesis and Characterization of Allyl Terpene Maleate Monomer - Nature
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Garlic Breath? Mouthwash Won't Work. Here's Why - American Council on Science and Health
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Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed Silylation of Terminal Olefins: A Silyl-Heck Reaction - Wiley Online Library
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Copper‐Catalyzed Borylative Allyl–Allyl Coupling Reaction - Semba - 2014 - Angewandte Chemie International Edition - Wiley Online Library
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Cobalt-Catalyzed Deprotection of Allyl Carboxylic Esters Induced by Hydrogen Atom Transfer - ACS Publications
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Gold(III) π‐Allyl Complexes - Rodriguez - 2020 - Angewandte Chemie International Edition - Wiley Online Library
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E‐Selective Radical Difunctionalization of Unactivated Alkynes: Preparation of Functionalized Allyl Alcohols from Aliphatic Alkynes - Wiley
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Catalytic Enantioselective Claisen Rearrangements of O‐Allyl β‐Ketoesters - Wiley Online Library
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Allyl and Benzyl Modified Aramid Nanofibers as an Enhancement in Polystyrene-Based Composites - Frontiers
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A comparison of hydrogen abstraction reaction between allyl-type monomers with thioxanthone-based photoinitiators without amine synergists - Frontiers
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Catalytic Enantioselective Claisen Rearrangements of O‐Allyl β‐Ketoesters - Wiley Online Library
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Formation of conjugates between β-lactoglobulin and allyl isothiocyanate: Effect on protein heat aggregation, foaming and emulsifying properties - ScienceDirect.com
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Silylium-Ion-Promoted Hydrosilylation of Aryl-Substituted Allenes: Interception by Cyclization of the Allyl-Cation Intermediate - ACS Publications
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Responses of Fungi Maggot (Bradysia impatiens Johannsen) to Allyl Isothiocyanate and High CO2 - Frontiers
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Allyl Isothiocyanate (AITC) Triggered Toxicity and FsYvc1 (a STRPC Family Member) Responded Sense in Fusarium solani - Frontiers
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Highly Regio- and Stereoselective Dehydration of Allylic Alcohols to Conjugated Dienes via 1,4- syn -Elimination with H - ACS Publications
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Selective [5,5]‐Sigmatropic Rearrangement by Assembly of Aryl Sulfoxides with Allyl Nitriles - Wiley Online Library
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Allyl methyl trisulfide protected against LPS-induced acute lung injury in mice via inhibition of the NF-κB and MAPK pathways - Frontiers
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Manganese-catalyzed cyclopropanation of allylic alcohols with sulfones - Nature
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Migratory allylic arylation of 1,n-enols enabled by nickel catalysis - Nature
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Integrating Allyl Electrophiles into Nickel‐Catalyzed Conjunctive Cross‐Coupling - Wiley Online Library
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Effect of allyl-isothiocyanate on survival and antimicrobial peptide expression following oral bacterial infections in Drosophila melanogaster - Frontiers
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Preformed π-Allyl Iron Complexes as Potent, Well-Defined Catalysts for the Allylic Substitution - Wiley Online Library
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Synthesis of a multifunctional hard monomer from rosin: the relationship of allyl structure in maleopimarate and UV-curing property | Scientific Reports - Nature
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Allyl isothiocyanate ameliorates lipid accumulation and inflammation in nonalcoholic fatty liver disease via the Sirt1/AMPK and NF-κB signaling pathways - Baishideng Publishing Group
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Synthesis of N-Heterocycles by Dehydrogenative Annulation of N-Allyl Amides with 1,3-Dicarbonyl Compounds - Wiley Online Library
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Allyl‐Palladium‐Catalyzed α,β‐Dehydrogenation of Carboxylic Acids via Enediolates - Wiley Online Library
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Umpolung carbonyls enable direct allylation and olefination of carbohydrates - Science | AAAS
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Hyperconjugation in Carbocations, a BLW Study with DFT approximation - Frontiers
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