Why is "Bidentate" trending?
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- Date: 2026-03-25 18:56:57
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Wikipedia Overview
In coordination chemistry, denticity refers to the number of donor groups in a given ligand that bind to the central metal atom in a coordination complex. In many cases, only one atom in the ligand binds to the metal, so the denticity equals one, and the ligand is said to be unidentate or monodentate. Ligands with more than one bonded atom are called multidentate or polydentate. The denticity of a ligand is described with the Greek letter κ ('kappa'). For example, κ6-EDTA describes an EDTA ligand that coordinates through 6 non-contiguous atoms.
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Search Interest Perspective
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Intralayer bidentate diammoniums for stable two-dimensional perovskites - Nature
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Unveiling Bidentate Nitrile-Driven Structural Degradation in High-Nickel Cathodes - ACS Publications
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Surface Passivation with Lattice-Matched Bidentate Ligand Enabling High-Performance Perovskite Quantum Dot Photodetectors - Wiley Online Library
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Bidentate enaminolate-based indium complexes as volatile precursors for atomic layer deposition - ScienceDirect.com
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Bidentate mixed-ligand strategy in dinuclear gold photoredox catalysis - Nature
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Dual Functionality of Bidentate Ligands for Optimized Charge Extraction in Lead Halide Perovskites: Implications for Perovskite Solar Cells - ACS Publications
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2D perovskites featuring intralayer bidentate ligands - Nature
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Highly Enantioselective Organocatalysis with Bidentate Halogen Bond Donors - Wiley Online Library
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Imine-Oxazoline (ImOx): A C1-Symmetric N,N-Bidentate Ligand for Asymmetric Catalysis - ACS Publications
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Structural elucidation, biological significance and computational approach of Copper(ii), Nickel(ii) and Cobalt(ii) with bidentate schiff base of N-(Napthalene-1-ylmethylene)isonicotinohydrazide - Nature
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The Potential of Ruthenium(II) Tris‐Bidentate Complexes as Multifunctional Photo‐Initiators - Wiley Online Library
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Bidentate N -ligand-assisted gold redox catalysis with hydrogen peroxide - Nature
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Achieving 32% Efficiency in Perovskite/Silicon Tandem Solar Cells with Bidentate-Anchored Superwetting Self-Assembled Molecular Layers - Wiley Online Library
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A Bidentate Ligand Featuring Ditopic Lewis Acids in the Second Sphere for Selective Substrate Capture and Activation - Wiley Online Library
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Liquid bidentate ligand for full ligand coverage towards efficient near-infrared perovskite quantum dot LEDs - Nature
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Bidentate Coordination Structure Facilitates High‐Voltage and High‐Utilization Aqueous Zn−I2 Batteries - Wiley Online Library
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N, N’-bidentate ligand anchored palladium catalysts on MOFs for efficient Heck reaction - Nature
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Bidentate Coordination Enables Anions-Regulated Solvation Structure for Advanced Aqueous Zinc Metal Batteries - Wiley Online Library
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Clusters Linked with a Bidentate Dithiol: Synthesis, Structure and Chirality Study - Wiley Online Library
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Defect Passivation and Stress Regulation via Bidentate Anchoring of Lewis Base for High‐Efficiency CsPbI3 Solar Cells - Wiley Online Library
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Redox Activity and Potentials of Bidentate N -Ligands Commonly Applied in Nickel-Catalyzed Cross-Coupling Reactions - Wiley Online Library
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Robust gold nanorods stabilized by bidentate N-heterocyclic-carbene–thiolate ligands - Nature
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Five‐ or six‐membered aluminum metallocyclic complexes containing N, N bidentate oxazolinyl‐indolate chelate ring: Synthesis, structural, and catalytic studies - Wiley Online Library
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Synthesis and Characterization of Bidentate (P^N)Gold(III) Fluoride Complexes: Reactivity Platforms for Reductive Elimination Studies - Wiley Online Library
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Bidentate Chiral Bis(imidazolium)-Based Halogen-Bond Donors: Synthesis and Applications in Enantioselective Recognition and Catalysis - Wiley Online Library
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A bidentate Polycomb Repressive-Deubiquitinase complex is required for efficient activity on nucleosomes - Nature
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Reaction of Mono‐ and Bidentate Phosphane Oxides with TiCl4 and Ti(NMe2)4 - Wiley Online Library
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Ultra-Strong, Humidity-Tolerant Thermoset Based on Dynamic Covalent Bond Integration Strategy via Boron−Nitrogen Bidentate Coordination - ACS Publications
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Rapid and selective separation of heavy metal ions from aquatic medium using a bidentate functionalized hybrid material - ScienceDirect.com
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Dearomatization of Electron-Deficient Phenols to ortho -Quinones: Bidentate Nitrogen-Ligated Iodine(V) Reagents - Wiley Online Library
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(A=K, Rb): Strong Second-Harmonic Generation and Sufficient Birefringence - Wiley Online Library
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Regio‐ and Stereoselective Functionalization Enabled by Bidentate Directing Groups - Wiley Online Library
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Catalytic and biological properties of palladium(II) complexes with bidentate Schiff base ligands - Wiley Online Library
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A Ni0 σ‐Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization - Wiley Online Library
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Polyethylene glycol-based bidentate ligands to enhance quantum dot and gold nanoparticle stability in biological media - Nature
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A Bidentate Iodine(III)‐Based Halogen‐Bond Donor as a Powerful Organocatalyst** - Wiley Online Library
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Cover Picture: Bidentate Chiral Bis(imidazolium)-Based Halogen-Bond Donors: Synthesis and Applications in Enantioselective Recognition and Catalysis (Angew. Chem. Int. Ed. 17/2020) - Wiley Online Library
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Antibacterial performance of heterocyclic organobismuth (III) complexes based on bidentate C,O-coordinating ligands: Synergism of ligand identity and coordination number - Wiley Online Library
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Synthesis and Structural Characterization of Four Bidentate Ortho-Hydroxy Schiff Bases and Their Copper (II) Complexes: Evaluation of Biological Activities, Antioxidant Power, and Molecular Docking Studies - Wiley Online Library
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Actinium coordination chemistry: A density functional theory study with monodentate and bidentate ligands - Wiley Online Library
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Lantern-type dinickel complexes: An exploration of possibilities for nickel–nickel bonding with bridging bidentate ligands - Wiley Online Library
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Competitive Formation Mechanism for Bidentate Passivation of Halogen Vacancies in Perovskite Based on 6-Chloropurine - Wiley Online Library
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Role for a bidentate ribonuclease in the initiation step of RNA interference - Nature
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Synthesis, structural characterization and molecular modelling of bidentate azo dye metal complexes: DNA interaction to antimicrobial and anticancer activities - Wiley Online Library
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Chelating effect in short polymers for the design of bidentate binders of increased affinity and selectivity - Nature
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A bidentate Lewis acid with a telluronium ion as an anion-binding site - Nature
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Synthesis of silver complexes with chelating bidentate N -heterocyclic ligands, their application in catalytic A - Wiley Online Library
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A Bidentate Iodine(III)‐Based Halogen‐Bond Donor as a Powerful Organocatalyst** - Wiley Online Library
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Co (II), Cu (II), Mn (II), Ni (II), Pd (II), and Pt (II) complexes of bidentate Schiff base ligand: Synthesis, crystal structure, and acute toxicity evaluation - Lupașcu - 2021 - Applied Organometallic Chemistry - Wiley Online Library
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-N Ligand, Naph-diPIM: Application to CpRu-Catalyzed Asymmetric Dehydrative C-, N-, and O-Allylation - Wiley Online Library
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Spectroscopic Identification of a Bidentate Binding Motif in the Anionic Magnesium–CO2 Complex ([ClMgCO2]−) - Wiley Online Library
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Squeezing Fluoride out of Water with a Neutral Bidentate Antimony(V) Lewis Acid - Hirai - 2015 - Angewandte Chemie - Wiley Online Library
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Bis(silylenyl)‐ and Bis(germylenyl)‐Substituted Ferrocenes: Synthesis, Structure, and Catalytic Applications of Bidentate Silicon(II)–Cobalt Complexes - Wang - 2012 - Angewandte Chemie International Edition - Wiley Online Library
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An Enantioselective Bidentate Auxiliary Directed Palladium‐Catalyzed Benzylic C−H Arylation of Amines Using a BINOL Phosphate Ligand - Wang - 2016 - Angewandte Chemie International Edition - Wiley Online Library
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Unsymmetric bidentate ligands in metal‐catalyzed carbonylation of alkenes - Nozaki - 2005 - The Chemical Record - Wiley Online Library
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A theory-driven synthesis of symmetric and unsymmetric 1,2-bis(diphenylphosphino)ethane analogues via radical difunctionalization of ethylene - Nature
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Self‐Assembled Supramolecular Bidentate Ligands for Aqueous Organometallic Catalysis - Wiley Online Library
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Synthesis of Triphosphorous Bidentate Phosphine–Phosphoramidite Ligands: Application in the Highly Enantioselective Hydrogenation of ortho‐Substituted Aryl Enamides - Wiley Online Library
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Mono- and Bidentate Phosphinanes—New Chiral Ligands and Their Application in Catalytic Asymmetric Hydrogenations - Wiley Online Library
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